![(R)-1-[(1S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylph osphine CAS 155830-69-6](https://www.watson-int.com/wp-content/uploads/2015/08/Structure-of-R-1-1S-2-Diphenylphosphinoferrocenylethyldi-tert-butylph-osphine-CAS-155830-69-6.png)
- Identification
- Properties
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Identification
CAS Number
155830-69-6
Name
(R)-1-ethyldi-tert-butylph osphine
Synonyms
(2R)-1-ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS)1,2,3,4,5-Cyclopentanepentayl, compd. with 1-ethyl]-2-(diphenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1) 155830-69-6 Josiphos SL-J002-1MFCD01074442(R)-1-ethyldi-tert-butylphosphine
SMILES
C(11P(c2ccccc2)c3ccccc3)P(C(C)(C)C)C(C)(C)C.11.
StdInChI
InChI=1S/C27H40P2.C5H10.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h8-13,15-18,21,24-25H,14,19-20H2,1-7H3;1-5H2;/t21-,24?,25?;;/m1../s1
StdInChIKey
KEERMMZARKKVBY-XOBZDMSASA-N
Molecular Formula
C32H40FeP2
Molecular Weight
542.45
MDL Number
MFCD01074442
Properties
Appearance
Orangecrystalline powder
Safety Data
WGK Germany
3
Specifications and Other Information of Our (R)-1-ethyldi-tert-butylph osphine CAS 155830-69-6
Identification Methods
1H-NMR; 31P-NMR
Purity
98% min
EE content
≥99.0%
Specific rotation
-412°±15°(c=0.5,CHCl3)
Shelf Life
2 years
Storage
The product is easy to be slowly oxidized when exposed to the air, and it needs to be vacuum-packed and refrigerated for long-term storage.
Known Application
Often used with precious metal palladium compounds for C-C coupling and C-N coupling; with precious metal rhodium and ruthenium compounds for asymmetric synthesis, etc.
Links
This product is developed by our R&D company Warshel Chemical Ltd (https://www.warshel.com/).
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