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(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine CAS 158923-11-6
- Identification
- Properties
- Safety Data
- Specifications & Other Information
- Links
- Quick Inquiry

Identification

CAS Number

158923-11-6

Name

(R)-(-)-1-ethyldi-t-butylphosphine

Synonyms

(2R)-1-ethyl]-2-(dicyclohexylphosphino)ferrocene (acc to CAS)1,2,3,4,5-Cyclopentanepentayl, compd. with 1-ethyl]-2-(dicyclohexylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1) 158923-11-6 Josiphos SL-J009-1MFCD08543435

SMILES

C(11P(C2CCCCC2)C3CCCCC3)P(C(C)(C)C)C(C)(C)C.11.

StdInChI

InChI=1S/C27H52P2.C5H10.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h21-25H,8-20H2,1-7H3;1-5H2;/t21-,24?,25?;;/m1../s1

StdInChIKey

QBLAUUUZOSXQMB-XOBZDMSASA-N

Molecular Formula

C32H52FeP2

Molecular Weight

554.55

MDL Number

MFCD08543435

Properties

Appearance

Orangecrystalline powder

Safety Data

WGK Germany

3

Specifications and Other Information of Our (R)-(-)-1-ethyldi-t-butylphosphine CAS 158923-11-6

Identification Methods

1H-NMR; 31P-NMR

Purity

98% min

EE content

≥99.0%

Specific rotation

-185°±10° (c＝0.5,CHCl3)

Shelf Life

2 years

Storage

The product is easy to be slowly oxidized when exposed to the air, and it needs to be vacuum-packed and refrigerated for long-term storage.light

Known Application

Often used with precious metal palladium compounds for C-C coupling and C-N coupling;It is used in asymmetric synthesis with precious metal rhodium and ruthenium compounds, etc.

Links

This product is developed by our R&D company Warshel Chemical Ltd (https://www.warshel.com/).

Quick Inquiry

Fill out our inquiry form and one of our experts will be in touch with you shortly.
https://www.watson-int.com/r-1-s-2-dicyclohexylphosphinoferrocenylethyldi-t-butylphosphine-cas-158923-11-6/

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